Please add the support description tag for other icons, for example:
  [Control]
  Icons=7
  Start=LibreOfficePortable.exe
  Start1=LibreOfficeBasePortable.exe
  Name1=LibreOffice Portable Base
+Description1=Database Management
  Start2=LibreOfficeCalcPortable.exe
  Name2=LibreOffice Portable Calc
+Description2=Spreadsheet program
  Start3=LibreOfficeDrawPortable.exe
  Name3=LibreOffice Portable Draw
+Description3=Vector graphics editor
  Start4=LibreOfficeImpressPortable.exe
  Name4=LibreOffice Portable Impress
+Description4=Presentation program
  Start5=LibreOfficeMathPortable.exe
  Name5=LibreOffice Portable Math
+Description5=Formula editor
  Start6=LibreOfficeWriterPortable.exe
  Name6=LibreOffice Portable Writer
+Description6=Word processor
  Start7=LibreOfficePortable.exe
  Name7=LibreOffice Portable
+Description7=Open-source office
  BaseAppID=TheDocumentFoundation.LibreOffice.Startcenter
Thanks.
 
      
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I've added it as a possible future feature: https://portableapps.com/node/28593
Sometimes, the impossible can become possible, if you're awesome!
Thanks