The Description on the download page says that Aquasnap works with multiple monitors.
https://portableapps.com/apps/utilities/aquasnap_portable
However, The Home page of AquaSnap now has a button that allows you to buy a license. The page that it brings you to indicates that multi-monitor support is a feature that is disabled unless you have paid for a License.
http://www.nurgo-software.com/products/aquasnap/28
In short, from what I can tell the the paid version has multi-monitor support while the freeware version does not.
The free version used to have multiple monitor support but that was removed some time ago.
Sometimes, the impossible can become possible, if you're awesome!