Using the latest, LO wouldn't exit from the drop down File menu, just from the 'X' close box.
New: gMKVExtractGUI (June 3, 2025), Platform 30.0.2 (Mar 27, 2025)
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Ctrl+Q is still working and with any file open the Menu works for me. Only in the overview it seems not working properly.
Update:It's gone in 5.1.4