from an unencrypted DVD and then convert the chapters to another file format?
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I use VOBmerge to combine the vobs into one long file, load into VirtualDubMod, and then output to avi or xvid. The merge into a single file seems to keep the audio in sync better than using individual 1-gb vob files.
I think also you could use SUPER video converter, VOB2Mpeg, many more.
To get help with video projects,you might want to check a forum dedicated to that subject.
Two very helpful ones are
www.videohelp.com/
and
http://forum.digital-digest.com/
Check the "Tools" section at videohelp.com, they have lots of converters and guides.