I have tested both on Windows 10 and 11 on two different computers both with 64-bit OS. All "direct" LibreOffice apps don't start with Portable Apps version of LibreOffice 220.127.116.11.
I have tried with different install paths with new clean installation and it does not work no matter how I have changed the install path. The path C:\PortableApps\LibreOfficePortable18.104.22.168\ was for example used.
It's the same behavior when starting from within the portableapps.com launcher as directly from installed path using windows explorer.
It's the same behavior with:
but there is a way to start Calc for example and that is by launching LibreOfficePortablePrevious.exe and then starting Calc from within LibreOffice.
Everything works just fine with LibreOffice Calc 22.214.171.124 and 126.96.36.199.
This problem only applies to version 188.8.131.52 and can hopefully be fixed in the final release of the 7.5.x branch.
Please verify that this works before releasing the portable 184.108.40.206 version.